Method, validation and sources

Formulation

Thermodynamic properties are computed with the IAPWS Industrial Formulation 1997 for the Thermodynamic Properties of Water and Steam (IAPWS-IF97, revised 2007), published by the International Association for the Properties of Water and Steam. The formulation divides the pressure–temperature plane into regions, each with its own equation:

Dynamic viscosity follows the IAPWS Formulation 2008 for the Viscosity of Ordinary Water Substance (without critical enhancement, as recommended for industrial use). Thermal conductivity follows the IAPWS Formulation 2011 for the Thermal Conductivity of Ordinary Water Substance, industrial variant.

Range of validity

0 °C ≤ T ≤ 800 °C for p ≤ 1000 bar (100 MPa), and 800 °C < T ≤ 2000 °C for p ≤ 500 bar (50 MPa). Outside this range no value is returned.

Validation

The calculation library is checked automatically against the computer-program verification values printed in the IAPWS-IF97 release for regions 1, 2, 3 and 5, the saturation curve and the region 2/3 boundary, and against the verification values of the IAPWS 2008 viscosity release. It was additionally compared on several hundred random states with an independent open-source implementation.

Limitations